Substituted nitrogen-bridged diazocines
نویسندگان
چکیده
Novel nitrogen-bridged diazocines (triazocines) were synthesized that carry a formyl or an acetyl group at the CH 2 NR-bridge and bromo- iodo-substituents distant phenyl ring. The photophysical properties investigated in acetonitrile water. As compared to previous approaches yields of intramolecular azo cyclizations increased (from ≈40 60%) using oxidative approach starting from corresponding aniline precursors. Z → E photoconversion are 80–85% thermal half-lives metastable configurations 31–74 min. Particularly, high (≈70%) water-soluble noteworthy, which makes them promising candidates for applications photopharmacology. halogen substituents allow further functionalization via cross-coupling reactions.
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Department of Chemistry, Indian Institute India. E-mail: [email protected]; Fax: + Department of Mechanical Engineering, I Mumbai 400076, India. E-mail: neeraj_k@i Polymer Chemistry Group, Department Laboratory, Uppsala University, Box 538, SE Polymers and Special Chemicals Group, PC (VSSC), Thiruvananthapuram, Kerala 69502 † Electronic supplementary information tables and NMR spectra. See...
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ژورنال
عنوان ژورنال: Beilstein Journal of Organic Chemistry
سال: 2021
ISSN: ['2195-951X', '1860-5397']
DOI: https://doi.org/10.3762/bjoc.17.107